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Liquid-phase exfoliation of F-diamane-like nanosheets

Abstract : Fluorinated single-layer diamond (“F-diamond”) is a new form of two-dimensional (2D) carbon allotrope. Herein, poly(dicarbon monofluoride) (C2F)n which is essentially made of stacked layers of “F-diamane” has been synthesized and exfoliated in a variety of solvents to yield well-dispersed ultrathin sheets. Microscopic and spectroscopic analyses revealed that the exfoliated nanosheets retained the “F-diamane”-like structure. The experimental results are also supported by density functional theory (DFT) calculations.
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Submitted on : Thursday, February 18, 2021 - 3:03:14 PM
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Xianjue Chen, Marc Dubois, Silvana Radescu, Aditya Rawal, Chuan Zhao. Liquid-phase exfoliation of F-diamane-like nanosheets. Carbon, 2021, 175, pp.124-130. ⟨10.1016/j.carbon.2020.12.081⟩. ⟨hal-03145625⟩



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