The Model of Emissions of Gases and Aerosols from Nature version 2.1 (MEGAN2.1): an extended and updated framework for modeling biogenic emissions, Geoscientific Model Development, vol.5, issue.6, pp.1471-1492, 2012. ,
DOI : 10.1029/2005JD006696
Atmospheric oxidation capacity sustained by a tropical forest, Nature, vol.104, issue.7188, pp.737-740, 2008. ,
DOI : 10.1021/jp048873t
The role of biogenic hydrocarbons in urban photochemical smog: Atlanta as a case study, Science, vol.241, issue.4872, pp.1473-1475, 1988. ,
DOI : 10.1126/science.3420404
Formation of Secondary Organic Aerosols Through Photooxidation of Isoprene, Science, vol.303, issue.5661, pp.1173-1176, 2004. ,
DOI : 10.1126/science.1092805
Unexpected Epoxide Formation in the Gas-Phase Photooxidation of Isoprene, Science, vol.276, issue.5315, pp.730-733, 2009. ,
DOI : 10.1126/science.276.5315.1052
URL : https://authors.library.caltech.edu/15078/2/1.pdf
Reactive intermediates revealed in secondary organic aerosol formation from isoprene, Proceedings of the National Academy of Sciences, vol.103, issue.15, pp.6640-6645, 2010. ,
DOI : 10.1029/98JD00320
URL : http://www.pnas.org/content/107/15/6640.full.pdf
The tropical forest and fire emissions experiment: Emission, chemistry, and transport of biogenic volatile organic compounds in the lower atmosphere over Amazonia, Journal of Geophysical Research, vol.93, issue.D2, p.18302, 2007. ,
DOI : 10.1007/978-94-009-3027-8
Isoprene and monoterpene fluxes from Central Amazonian rainforest inferred from tower-based and airborne measurements, and implications on the atmospheric chemistry and the local carbon budget, Atmospheric Chemistry and Physics, vol.7, issue.11, pp.2855-2879, 2007. ,
DOI : 10.5194/acp-7-2855-2007
URL : https://hal.archives-ouvertes.fr/hal-00296243
The MCM v3.3.1 degradation scheme for isoprene, Atmospheric Chemistry and Physics, vol.15, issue.20, pp.11433-11459, 2015. ,
DOI : 10.5194/acp-15-11433-2015-supplement
URL : https://hal.archives-ouvertes.fr/hal-00295497
Peroxy radical isomerization in the oxidation of isoprene, Physical Chemistry Chemical Physics, vol.114, issue.12, pp.13607-13613, 2011. ,
DOI : 10.1021/jp104828a
URL : https://authors.library.caltech.edu/24329/1/Crounse2011p14390Physical_chemistry_chemical_physics_PCCP.pdf
Production of methyl vinyl ketone and methacrolein via the hydroperoxyl pathway of isoprene oxidation, Atmospheric Chemistry and Physics, vol.13, issue.11, pp.5715-5730, 2013. ,
DOI : 10.5194/acp-13-5715-2013-supplement
Submicron particle mass concentrations and sources in the Amazonian wet season (AMAZE-08), Atmospheric Chemistry and Physics, vol.15, issue.7, pp.3687-3701, 2015. ,
DOI : 10.5194/acp-15-3687-2015-supplement
URL : http://doi.org/10.5194/acp-15-3687-2015
Conversion of hydroperoxides to carbonyls in field and laboratory instrumentation: Observational bias in diagnosing pristine versus anthropogenically controlled atmospheric chemistry, Geophysical Research Letters, vol.47, issue.20, pp.8645-8651, 2014. ,
DOI : 10.1021/es4011064
Peroxy radical kinetics resulting from the OH-initiated oxidation of 1,3-butadiene, 2,3-dimethyl-1,3-butadiene and isoprene, Journal of Atmospheric Chemistry, vol.29, issue.3, pp.267-298, 1998. ,
DOI : 10.1023/A:1005940332441
Hydroxyl Radical Recycling in Isoprene Oxidation Driven by Hydrogen Bonding and Hydrogen Tunneling: The Upgraded LIM1 Mechanism, The Journal of Physical Chemistry A, vol.118, issue.38, pp.8625-8643, 2014. ,
DOI : 10.1021/jp5033146
URL : https://lirias.kuleuven.be/bitstream/123456789/465935/1/LIM1_JPC_just-accepted_11-7-2014.pdf
Detection of HO<sub>2</sub> by laser-induced fluorescence: calibration and interferences from RO<sub>2</sub> radicals, Atmospheric Measurement Techniques, vol.4, issue.6, pp.1209-1225, 2011. ,
DOI : 10.1021/jp048096x
Airborne intercomparison of nitric oxide measurement techniques, Journal of Geophysical Research, vol.90, issue.D2, pp.1995-2008, 1987. ,
DOI : 10.1029/JD090iD07p12875
Overview: oxidant and particle photochemical processes above a south-east Asian tropical rainforest (the OP3 project): introduction, rationale, location characteristics and tools, Atmospheric Chemistry and Physics, vol.10, issue.1, pp.169-199, 2010. ,
DOI : 10.5194/acp-10-169-2010
Let's abandon the " high NO x " and " low NO x " terminology, IGAC News, vol.50, pp.3-4, 2013. ,
An Observational Perspective on the Atmospheric Impacts of Alkyl and Multifunctional Nitrates on Ozone and Secondary Organic Aerosol, Chemical Reviews, vol.113, issue.8, pp.5848-5870, 2013. ,
DOI : 10.1021/cr300520x
Measurements of volatile organic compounds in the earth's atmosphere using proton-transfer-reaction mass spectrometry, Mass Spectrometry Reviews, vol.38, issue.224, pp.223-257, 2007. ,
DOI : 10.1029/2003GL017933
Rapid formation of isoprene photo-oxidation products observed in Amazonia, Atmospheric Chemistry and Physics, vol.9, issue.20, pp.7753-7767, 2009. ,
DOI : 10.5194/acp-9-7753-2009
URL : https://doi.org/10.5194/acpd-9-13629-2009
Observational Insights into Aerosol Formation from Isoprene, Environmental Science & Technology, vol.47, issue.20, pp.11403-11413, 2013. ,
DOI : 10.1021/es4011064
URL : http://nature.berkeley.edu/ahg/pubs/Worton%20ES%26T%202013%20es4011064.pdf
Observation of isoprene hydroxynitrates in the southeastern United States and implications for the fate of NO<sub><i>x</i></sub>, Atmospheric Chemistry and Physics, vol.15, issue.19, pp.11257-11272, 2015. ,
DOI : 10.5194/acp-15-11257-2015-supplement
Introduction: Observations and Modeling of the Green Ocean Amazon (GoAmazon2014/5), Atmospheric Chemistry and Physics, vol.16, issue.8, pp.4785-4797, 2016. ,
DOI : 10.5194/acp-16-4785-2016-supplement
Rapid deposition of oxidized biogenic compounds to a temperate forest, Proceedings of the National Academy of Sciences, vol.5, issue.1, pp.392-401, 2015. ,
DOI : 10.1029/2000JD900746
URL : http://www.pnas.org/content/112/5/E392.full.pdf
Airborne Flux Measurements of BVOCs above Californian Oak Forests: Experimental Investigation of Surface and Entrainment Fluxes, OH Densities, and Damk??hler Numbers, Journal of the Atmospheric Sciences, vol.70, issue.10, pp.3277-3287, 2013. ,
DOI : 10.1175/JAS-D-13-054.1
URL : http://nature.berkeley.edu/ahg/pubs/Karl%20et%20al%202013%20JAS.pdf
Mass spectral characterization of submicron biogenic organic particles in the Amazon Basin, Geophysical Research Letters, vol.39, issue.D24, p.20806, 2009. ,
DOI : 10.1029/2009GL039880
Sources and properties of Amazonian aerosol particles, Reviews of Geophysics, vol.93, issue.D20, p.2002, 2010. ,
DOI : 10.1080/10473289.2002.10470813
URL : http://onlinelibrary.wiley.com/doi/10.1029/2008RG000280/pdf
Overview of the Focused Isoprene eXperiment at the California Institute of Technology (FIXCIT): mechanistic chamber studies on the oxidation of biogenic compounds, Atmospheric Chemistry and Physics, vol.14, issue.24, pp.13531-13549, 2014. ,
DOI : 10.1021/es4011064
) within and above a tropical forest canopy in the wet season, Journal of Geophysical Research, vol.16, issue.D10, pp.16765-16772, 1990. ,
DOI : 10.1016/0004-6981(82)90399-7
column measurements, Geophysical Research Letters, vol.4, issue.9, pp.1856-1860, 2013. ,
DOI : 10.5194/amt-4-1929-2011
Evaluation of HO<sub>x</sub> sources and cycling using measurement-constrained model calculations in a 2-methyl-3-butene-2-ol (MBO) and monoterpene (MT) dominated ecosystem, Atmospheric Chemistry and Physics, vol.13, issue.4, pp.2031-2044, 2013. ,
DOI : 10.1039/c2cp40388a
On inferring isoprene emission surface flux from atmospheric boundary layer concentration measurements, Atmospheric Chemistry and Physics, vol.9, issue.11, pp.3629-3640, 2009. ,
DOI : 10.5194/acp-9-3629-2009
Kinetics and Products of the Reaction of the First-Generation Isoprene Hydroxy Hydroperoxide (ISOPOOH) with OH, The Journal of Physical Chemistry A, vol.120, issue.9, pp.1441-1451, 2016. ,
DOI : 10.1021/acs.jpca.5b06532
Tropospheric nitric oxide measurements over the Amazon Basin, Journal of Geophysical Research, vol.93, issue.D2, pp.1396-1406, 1988. ,
DOI : 10.1029/JD093iD02p01407
Isoprene chemistry in pristine and polluted Amazon environments: Eulerian and Lagrangian model frameworks and the strong bearing they have on our understanding of surface ozone and predictions of rainforest exposure to this priority pollutant, Atmospheric Chemistry and Physics Discussions, vol.15, issue.17, pp.24251-24310, 2015. ,
DOI : 10.5194/acpd-15-24251-2015-supplement
Rainforest Aerosols as Biogenic Nuclei of Clouds and Precipitation in the Amazon, Science, vol.452, issue.7188, pp.1513-1516, 2010. ,
DOI : 10.1038/nature06870
Effects of additional nonmethane volatile organic compounds, organic nitrates, and direct emissions of oxygenated organic species on global tropospheric chemistry, Journal of Geophysical Research, vol.24, issue.4, p.6309, 2007. ,
DOI : 10.1021/jp971908n
URL : http://onlinelibrary.wiley.com/doi/10.1029/2005JD006556/pdf
Emission of nitric oxide (NO) from tropical forest soils and exchange of NO between the forest canopy and atmospheric boundary layers, Journal of Geophysical Research, vol.92, issue.D10, pp.16755-16764, 1990. ,
DOI : 10.1029/JD092iD02p02173
Land use change and biogeochemical controls of nitrogen oxide emissions from soils in eastern Amazonia, Global Biogeochemical Cycles, vol.100, issue.1, pp.31-46, 1999. ,
DOI : 10.1029/95JD00370
URL : http://onlinelibrary.wiley.com/doi/10.1029/1998GB900019/pdf
Controls on soil nitrogen oxide emissions from forest and pastures in the Brazilian Amazon, Global Biogeochemical Cycles, vol.17, issue.suppl. 1, pp.1021-1030, 2001. ,
DOI : 10.1146/annurev.es.17.110186.001033
URL : http://onlinelibrary.wiley.com/doi/10.1029/2000GB001349/pdf
in a tropical forest system, Journal of Geophysical Research, vol.93, issue.D2, pp.1389-1395, 1988. ,
DOI : 10.1029/JD093iD02p01407
Nitrogen management is essential to prevent tropical oil palm plantations from causing ground-level ozone pollution, Proceedings of the National Academy of Sciences, vol.51, issue.3, pp.18447-18451, 2009. ,
DOI : 10.1111/j.1365-313X.2007.03157.x
emissions and the role of canopy processes, Journal of Geophysical Research, vol.100, issue.D16, p.4298, 2002. ,
DOI : 10.1029/95JD00370
Photochemistry of biogenic emissions over the Amazon forest, Journal of Geophysical Research, vol.93, issue.D2, pp.1477-1486, 1988. ,
DOI : 10.1029/JD093iD02p01407
URL : https://dash.harvard.edu/bitstream/handle/1/14121764/Photochemistry%20of%20biogenic%20emissions%20over%20the%20Amazon%20forest.pdf?sequence=1
The Amazon basin in transition, Nature, vol.21, issue.7381, pp.321-328, 2012. ,
DOI : 10.1111/j.1529-8817.2003.00774.x
NO<sub>x</sub> and O<sub>3</sub> above a tropical rainforest: an analysis with a global and box model, Atmospheric Chemistry and Physics, vol.10, issue.21, pp.10607-10620, 2010. ,
DOI : 10.5194/acp-10-10607-2010-supplement
Introduction: Observations and Modeling of the Green Ocean Amazon (GoAmazon2014/5), Atmospheric Chemistry and Physics Discussions, vol.15, issue.21, pp.30175-30210, 2015. ,
DOI : 10.5194/acpd-15-30175-2015-supplement
Estimates of global terrestrial isoprene emissions using MEGAN (Model of Emissions of Gases and Aerosols from Nature), Atmospheric Chemistry and Physics, vol.6, issue.11, pp.3181-3210, 2006. ,
DOI : 10.5194/acp-6-3181-2006
URL : https://hal.archives-ouvertes.fr/hal-00295995
An online ultra-high sensitivity Proton-transfer-reaction mass-spectrometer combined with switchable reagent ion capability (PTR+SRI???MS), International Journal of Mass Spectrometry, vol.286, issue.1, pp.32-38, 2009. ,
DOI : 10.1016/j.ijms.2009.06.006
Production of methyl vinyl ketone and methacrolein via the hydroperoxyl pathway of isoprene oxidation, Atmospheric Chemistry and Physics, vol.13, issue.11, pp.5715-5730, 2013. ,
DOI : 10.5194/acp-13-5715-2013-supplement
Overview of the Focused Isoprene eXperiment at the California Institute of Technology (FIXCIT): mechanistic chamber studies on the oxidation of biogenic compounds, Atmospheric Chemistry and Physics, vol.14, issue.24, pp.13531-13549, 2014. ,
DOI : 10.1021/es4011064
Measurements of acetone and other gas phase product yields from the OH-initiated oxidation of terpenes by proton-transfer-reaction mass spectrometry (PTR-MS), Atmospheric Environment, vol.35, issue.35, pp.356181-6191, 2001. ,
DOI : 10.1016/S1352-2310(01)00385-5
Conversion of hydroperoxides to carbonyls in field and laboratory instrumentation: Observational bias in diagnosing pristine versus anthropogenically controlled atmospheric chemistry, Geophysical Research Letters, vol.47, issue.20, pp.418645-8651, 2014. ,
DOI : 10.1021/es4011064
Pathway, Environmental Science & Technology, vol.49, issue.1, pp.250-258, 2015. ,
DOI : 10.1021/es5034298
URL : https://hal.archives-ouvertes.fr/hal-01518006
The MCM v3.3.1 degradation scheme for isoprene, Atmospheric Chemistry and Physics, vol.15, issue.20, pp.11433-11459, 2015. ,
DOI : 10.5194/acp-15-11433-2015-supplement
URL : https://hal.archives-ouvertes.fr/hal-00295497
Kinetics and products of the reaction of the first-generation isoprene hydroxy hydroperoxide (ISOPOOH) with OH, J. Phys. Chem. A, vol.120, issue.9, pp.1441-1451, 2016. ,
Global modeling of tropospheric chemistry with assimilated meteorology: Model description and evaluation, Journal of Geophysical Research: Atmospheres, vol.37, issue.D19, pp.23073-23095, 2001. ,
DOI : 10.1023/A:1006415919030
URL : http://onlinelibrary.wiley.com/doi/10.1029/2001JD000807/pdf
Ozone and organic nitrates over the eastern United States: Sensitivity to isoprene chemistry, Journal of Geophysical Research: Atmospheres, vol.45, issue.37, pp.11256-11268, 2013. ,
DOI : 10.1016/j.atmosenv.2011.07.054
URL : http://onlinelibrary.wiley.com/doi/10.1002/jgrd.50817/pdf
Rapid deposition of oxidized biogenic compounds to a temperate forest, Proceedings of the National Academy of Sciences, vol.5, issue.1, pp.392-401, 2015. ,
DOI : 10.1029/2000JD900746
URL : http://www.pnas.org/content/112/5/E392.full.pdf
Gas Phase Production and Loss of Isoprene Epoxydiols, The Journal of Physical Chemistry A, vol.118, issue.7, pp.1237-1246, 2014. ,
DOI : 10.1021/jp4107958
URL : https://authors.library.caltech.edu/43756/7/jp4107958_si_001.pdf
, The Journal of Physical Chemistry A, vol.119, issue.19, pp.4562-4572, 2015.
DOI : 10.1021/jp5107058
Dihydroxycarbonyl Compounds from Isoprene Oxidation, The Journal of Physical Chemistry A, vol.120, issue.1, pp.106-117, 2016. ,
DOI : 10.1021/acs.jpca.5b10335
URL : https://authors.library.caltech.edu/63562/2/jp5b10335_si_001.pdf
Evaluation of HO<sub>x</sub> sources and cycling using measurement-constrained model calculations in a 2-methyl-3-butene-2-ol (MBO) and monoterpene (MT) dominated ecosystem, Atmospheric Chemistry and Physics, vol.13, issue.4, pp.2031-204416851, 1990. ,
DOI : 10.1039/c2cp40388a
The tropospheric degradation of volatile organic compounds: a protocol for mechanism development, Atmospheric Environment, vol.31, issue.1, pp.81-104, 1997. ,
DOI : 10.1016/S1352-2310(96)00105-7
URL : https://hal.archives-ouvertes.fr/hal-00300962
Protocol for the development of the Master Chemical Mechanism, MCM v3 (Part A): tropospheric degradation of non-aromatic volatile organic compounds, Atmospheric Chemistry and Physics, vol.3, issue.1, pp.161-180, 2003. ,
DOI : 10.5194/acp-3-161-2003
URL : https://hal.archives-ouvertes.fr/hal-00300962
Atmospheric oxidation capacity sustained by a tropical forest, Nature, vol.104, issue.7188, pp.737-740, 2008. ,
DOI : 10.1021/jp048873t
Detection of HO<sub>2</sub> by laser-induced fluorescence: calibration and interferences from RO<sub>2</sub> radicals, Atmospheric Measurement Techniques, vol.4, issue.6, pp.1209-1225, 2011. ,
DOI : 10.1021/jp048096x
Overview: oxidant and particle photochemical processes above a south-east Asian tropical rainforest (the OP3 project): introduction, rationale, location characteristics and tools, Atmospheric Chemistry and Physics, vol.10, issue.1, pp.169-199, 2010. ,
DOI : 10.5194/acp-10-169-2010
Peroxy radical chemistry and the control of ozone photochemistry at Mace Head, Ireland during the summer of 2002, Atmospheric Chemistry and Physics, vol.6, issue.8, pp.2193-2214, 2006. ,
DOI : 10.5194/acp-6-2193-2006
URL : https://hal.archives-ouvertes.fr/hal-00295945
dependence of isoprene oxidation, Journal of Geophysical Research, vol.103, issue.D12, p.11310, 2004. ,
DOI : 10.1029/98JD00074
Emission of nitric oxide (NO) from tropical forest soils and exchange of NO between the forest canopy and atmospheric boundary layers, Journal of Geophysical Research, vol.92, issue.D10, pp.16755-16764, 1990. ,
DOI : 10.1029/JD092iD02p02173
Land use change and biogeochemical controls of nitrogen oxide emissions from soils in eastern Amazonia, Global Biogeochemical Cycles, vol.100, issue.1, pp.31-46, 1999. ,
DOI : 10.1029/95JD00370
Controls on soil nitrogen oxide emissions from forest and pastures in the Brazilian Amazon, Global Biogeochemical Cycles, vol.17, issue.suppl. 1, pp.1021-1030, 2001. ,
DOI : 10.1146/annurev.es.17.110186.001033
in a tropical forest system, Journal of Geophysical Research, vol.93, issue.D2, pp.1389-1395, 1988. ,
DOI : 10.1029/JD093iD02p01407
Global soil-biogenic NOx emissions and the role of canopy processes, D16):ACH 9, 2002. ,
Cycling of NOx in tropical forest canopies. Microbioal production and consumption of greenhouse gases: methane, nitrogen oxides, and halomethanes, pp.237-253, 1991. ,
Steps towards a mechanistic model of global soil nitric oxide emissions: implementation and space based-constraints, Atmospheric Chemistry and Physics, vol.12, issue.16, pp.7779-7795, 2012. ,
DOI : 10.5194/acp-12-7779-2012
Evaluated kinetic and photochemical data for atmospheric chemistry: Volume II – gas phase reactions of organic species, Atmospheric Chemistry and Physics, vol.6, issue.11, pp.3625-4055, 2006. ,
DOI : 10.5194/acp-6-3625-2006
On inferring isoprene emission surface flux from atmospheric boundary layer concentration measurements, Atmospheric Chemistry and Physics, vol.9, issue.11, pp.3629-3640, 2009. ,
DOI : 10.5194/acp-9-3629-2009
Isoprene and monoterpene fluxes from Central Amazonian rainforest inferred from tower-based and airborne measurements, and implications on the atmospheric chemistry and the local carbon budget, Atmospheric Chemistry and Physics, vol.7, issue.11, pp.2855-2879, 2007. ,
DOI : 10.5194/acp-7-2855-2007
URL : https://hal.archives-ouvertes.fr/hal-00296243
The tropical forest and fire emissions experiment: Emission, chemistry, and transport of biogenic volatile organic compounds in the lower atmosphere over Amazonia, Journal of Geophysical Research, vol.93, issue.D2, p.18302, 2007. ,
DOI : 10.1007/978-94-009-3027-8
Hydroxyl Radical Recycling in Isoprene Oxidation Driven by Hydrogen Bonding and Hydrogen Tunneling: The Upgraded LIM1 Mechanism, The Journal of Physical Chemistry A, vol.118, issue.38, pp.8625-8643, 2014. ,
DOI : 10.1021/jp5033146
URL : https://lirias.kuleuven.be/bitstream/123456789/465935/1/LIM1_JPC_just-accepted_11-7-2014.pdf